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High iso Aldehyde Selectivity in the Hydroformylation of Short-Chain Alkenes.
Iu, Leo; Fuentes, José A; Janka, Mesfin E; Fontenot, Kevin J; Clarke, Matthew L.
Afiliação
  • Iu L; EaStCHEM School of Chemistry, University of St Andrews, Purdie Building, North Haugh, St Andrews, KY16 9ST, UK.
  • Fuentes JA; EaStCHEM School of Chemistry, University of St Andrews, Purdie Building, North Haugh, St Andrews, KY16 9ST, UK.
  • Janka ME; Eastman Chemical Company, 200 South Wilcox Drive, Kingsport, TN, 37660, USA.
  • Fontenot KJ; Eastman Chemical Company, 200 South Wilcox Drive, Kingsport, TN, 37660, USA.
  • Clarke ML; EaStCHEM School of Chemistry, University of St Andrews, Purdie Building, North Haugh, St Andrews, KY16 9ST, UK.
Angew Chem Int Ed Engl ; 58(7): 2120-2124, 2019 Feb 11.
Article em En | MEDLINE | ID: mdl-30561885
The hydroformylation of propene to give predominantly iso-butanal has been achieved; class-leading selectivity is possible even at higher temperatures that deliver fast conversion. Racemic rhodium complexes of bidentate phospholane phosphites derived from tropos-biphenols and unusual solvent systems are the key to the selectivity observed.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2019 Tipo de documento: Article País de publicação: Alemanha
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2019 Tipo de documento: Article País de publicação: Alemanha