Synthesis of 2-Aryloxy-1,3-dienes from Phenols and Propargyl Carbonates.
J Am Chem Soc
; 141(1): 84-88, 2019 01 09.
Article
em En
| MEDLINE
| ID: mdl-30563331
ABSTRACT
A convenient method for the synthesis of 1,3-dienes from readily available compounds is reported. 2-Aryoxy-1,3-dienes are produced stereoselectively by a nickel-catalyzed reaction of propargyl carbonates with phenols. Functional group tolerance is broad to allow iodo, formyl, and boryl groups. The resulting 1,3-dienes are of much synthetic value because they can participate in a wide variety of reactions, including the Diels-Alder reaction.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
J Am Chem Soc
Ano de publicação:
2019
Tipo de documento:
Article
País de afiliação:
Japão