Synthesis of 2-Aryloxy-1,3-dienes from Phenols and Propargyl Carbonates.

Ishida, Naoki; Hori, Yusaku; Okumura, Shintaro; Murakami, Masahiro

Ishida, Naoki; Hori, Yusaku; Okumura, Shintaro; Murakami, Masahiro.

Afiliação

Ishida N; Department of Synthetic Chemistry and Biological Chemistry , Kyoto University , Katsura, Kyoto 615-8510 , Japan.
Hori Y; Department of Synthetic Chemistry and Biological Chemistry , Kyoto University , Katsura, Kyoto 615-8510 , Japan.
Okumura S; Department of Synthetic Chemistry and Biological Chemistry , Kyoto University , Katsura, Kyoto 615-8510 , Japan.
Murakami M; Department of Synthetic Chemistry and Biological Chemistry , Kyoto University , Katsura, Kyoto 615-8510 , Japan.

J Am Chem Soc ; 141(1): 84-88, 2019 01 09.

Article em En | MEDLINE | ID: mdl-30563331

ABSTRACT

ABSTRACT

A convenient method for the synthesis of 1,3-dienes from readily available compounds is reported. 2-Aryoxy-1,3-dienes are produced stereoselectively by a nickel-catalyzed reaction of propargyl carbonates with phenols. Functional group tolerance is broad to allow iodo, formyl, and boryl groups. The resulting 1,3-dienes are of much synthetic value because they can participate in a wide variety of reactions, including the Diels-Alder reaction.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Am Chem Soc Ano de publicação: 2019 Tipo de documento: Article País de afiliação: Japão

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