The correlation-bound anion of p-chloroaniline.
J Chem Phys
; 150(16): 161103, 2019 Apr 28.
Article
em En
| MEDLINE
| ID: mdl-31042894
The p-chloroaniline anion was generated by Rydberg electron transfer and studied via velocity-map imaging anion photoelectron spectroscopy. The vertical detachment energy (VDE) of the p-chloroaniline anion was measured to be 6.6 meV. This value is in accord with the VDE of 10 meV calculated by Skurski and co-workers. They found the binding of the excess electron in the p-chloroaniline anion to be due almost entirely to electron correlation effects, with only a small contribution from the long-range dipole potential. As such, the p-chloroaniline anion is the first essentially correlation-bound anion to be observed experimentally.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
J Chem Phys
Ano de publicação:
2019
Tipo de documento:
Article
País de afiliação:
Estados Unidos
País de publicação:
Estados Unidos