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Efficient Electrogenerated Chemiluminescence of Pyrrolopyrrole Aza-BODIPYs in the Near-Infrared Region with Tripropylamine: Involving Formation of S2 and T2 States.
Ishimatsu, Ryoichi; Shintaku, Hirosato; Kage, Yuto; Kamioka, Misaki; Shimizu, Soji; Nakano, Koji; Furuta, Hiroyuki; Imato, Toshihiko.
Afiliação
  • Ishimatsu R; Department of Applied Chemistry, Graduate School of Engineering , Kyushu University , 744 Motooka, Nishi-ku , Fukuoka 819-0395 , Japan.
  • Shintaku H; Department of Applied Chemistry, Graduate School of Engineering , Kyushu University , 744 Motooka, Nishi-ku , Fukuoka 819-0395 , Japan.
  • Kage Y; Department of Applied Chemistry, Graduate School of Engineering , Kyushu University , 744 Motooka, Nishi-ku , Fukuoka 819-0395 , Japan.
  • Kamioka M; Department of Applied Chemistry, Graduate School of Engineering , Kyushu University , 744 Motooka, Nishi-ku , Fukuoka 819-0395 , Japan.
  • Shimizu S; Department of Applied Chemistry, Graduate School of Engineering , Kyushu University , 744 Motooka, Nishi-ku , Fukuoka 819-0395 , Japan.
  • Nakano K; Center for Molecular Systems (CMS) , Kyushu University , 744 Motooka, Nishi-ku , Fukuoka 819-0395 , Japan.
  • Furuta H; Department of Applied Chemistry, Graduate School of Engineering , Kyushu University , 744 Motooka, Nishi-ku , Fukuoka 819-0395 , Japan.
  • Imato T; Department of Applied Chemistry, Graduate School of Engineering , Kyushu University , 744 Motooka, Nishi-ku , Fukuoka 819-0395 , Japan.
J Am Chem Soc ; 141(30): 11791-11795, 2019 07 31.
Article em En | MEDLINE | ID: mdl-31314503
ABSTRACT
Efficient electrogenerated chemiluminescences (ECLs) of three pyrrolopyrrole aza-BODIPYs in the near-infrared region by using tripropylamine as a coreactant are reported. Kinetic analysis based on Marcus theory indicates the direct formation of S2 and T2 states through the electron transfer reaction, which affects the ECL efficiencies.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Am Chem Soc Ano de publicação: 2019 Tipo de documento: Article País de afiliação: Japão

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Am Chem Soc Ano de publicação: 2019 Tipo de documento: Article País de afiliação: Japão
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