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Ion-assisted construction of Sb/N-doped graphene as an anode for Li/Na ion batteries.
Nanotechnology ; 31(9): 095404, 2019 Nov 14.
Artigo em Inglês | MEDLINE | ID: mdl-31726430
Although secondary batteries are common in many fields, new electrode materials with a reasonable structure are desired for high battery performance. Herein, Sb/N-doped graphene nanosheets (NGNS-Q) were constructed with the help of 7,7,8,8-tetracyanoquinodimethane anions (TCNQ·-). TCNQ·- were used to anchor Sb3+ into the graphene layer by electrostatic interaction, which improves the distribution of Sb nanoparticles. Meanwhile, TCNQ·- act as a N source to form N-doped graphene, enhancing the electron conductivity of the composite. Benefiting from the stable structure and good conductivity, the Sb/NGNS-Q composite achieved good electrochemical battery performance for Li/Na ion batteries (LIBs/SIBs). At a current density of 0.1 A g-1, Sb/NGNS-Q exhibited a capacity of 615 mAh g-1 after cycling 200 times and 240 mAh g-1 after 100 cycles for LIBs and SIBs, respectively.





Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Nanotechnology Ano de publicação: 2019 Tipo de documento: Artigo