A convenient reagent for the conversion of aldoximes into nitriles and isonitriles.

Zhang, Wei; Lin, Jin-Hong; Zhang, Pengfei; Xiao, Ji-Chang

Zhang, Wei; Lin, Jin-Hong; Zhang, Pengfei; Xiao, Ji-Chang.

Afiliação

Zhang W; Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032, China. jchxiao@sioc.ac.cn.

Chem Commun (Camb) ; 56(46): 6221-6224, 2020 Jun 11.

Article em En | MEDLINE | ID: mdl-32369052

ABSTRACT

ABSTRACT

For the dehydroxylation of aldoximes with 4-nitro-1-((trifluoromethyl)sulfonyl)-imidazole (NTSI), slight modifications of reaction conditions resulted in significantly different reaction paths to provide either nitriles or isonitriles. The challenging conversion of aldoximes into isonitriles was achieved under mild conditions.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2020 Tipo de documento: Article País de afiliação: China

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