Boosting Circularly Polarized Luminescence of Organic Conjugated Systems via Twisted Intramolecular Charge Transfer.
Research (Wash D C)
; 2020: 3839160, 2020.
Article
em En
| MEDLINE
| ID: mdl-32395717
Realizing a high luminescence dissymmetry factor (g lum) is a paramount yet challenging issue in the research field of circularly polarized luminescence (CPL). Here, we reported a novel set of organic conjugated systems with twisted intramolecular charge transfer (TICT) characteristics based on conjugated o-carborane-binaphthyl dyads composing of binaphthyl units as chiral electron donors and o-carborane units as achiral electron acceptors, demonstrating intense CPL with large g lum values. Interestingly, single-crystalline o-1 exhibited a high-level brightness and a large g lum factor as high as +0.13, whereas single-crystalline o-2 processed a relatively low brightness with a decreased g lum value to -0.04. The significant diversity of CPL-active properties was triggered by the selective introduction of o-carborane units onto the binaphthyl units. Benefiting from the large magnetic dipole transition moments in TICT states, the CPL activity of TICT o-carborane-based materials exhibited amplified circular polarization. This study provides an efficient molecular engineering strategy for the rational design and development of highly efficient CPL-active materials.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Research (Wash D C)
Ano de publicação:
2020
Tipo de documento:
Article
País de afiliação:
China
País de publicação:
Estados Unidos