Your browser doesn't support javascript.
loading
Hydrogen nuclear mean kinetic energy in water down the Mariana Trench: Competition of pressure and salinity.
Bocedi, Alessio; Romanelli, Giovanni; Andreani, Carla; Senesi, Roberto.
Afiliação
  • Bocedi A; Università degli Studi di Roma "Tor Vergata", Dipartimento di Scienze e Tecnologie Chimiche, Via della Ricerca Scientifica 1, Rome 00133, Italy.
  • Romanelli G; ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11OQX, United Kingdom.
  • Andreani C; Università degli Studi di Roma "Tor Vergata", Dipartimento di Fisica and NAST Center, Via della Ricerca Scientifica 1, Rome 00133, Italy.
  • Senesi R; Università degli Studi di Roma "Tor Vergata", Dipartimento di Fisica and NAST Center, Via della Ricerca Scientifica 1, Rome 00133, Italy.
J Chem Phys ; 153(13): 134306, 2020 Oct 07.
Article em En | MEDLINE | ID: mdl-33032407
The Mariana Trench is one of the most famous and extreme environments on our planet. We report experimental values of the hydrogen nuclear mean kinetic energy in water samples at the same physical and chemical conditions than in the Challenger Deep within the Mariana Trench: a pressure of 1092 bars, a temperature of 1 °C, and a salinity of 35 g of salt per kg of water. Results were obtained by deep inelastic neutron scattering at the VESUVIO spectrometer at ISIS. We find that the effect of pressure is to increase the hydrogen nuclear mean kinetic energy with respect to ambient conditions, while ions in the solution have the opposite effect. These results confirm the recent state-of-the-art simulations of the nuclear hydrogen dynamics in water. The changes in the nuclear mean kinetic energy likely correspond to different isotopic fractionation values in the Challenger Deep compared to standard sea water.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Chem Phys Ano de publicação: 2020 Tipo de documento: Article País de afiliação: Itália País de publicação: Estados Unidos

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Chem Phys Ano de publicação: 2020 Tipo de documento: Article País de afiliação: Itália País de publicação: Estados Unidos