A Z-type PGeP pincer germylene ligand in a T-shaped palladium(0) complex.
Chem Commun (Camb)
; 56(90): 14095-14097, 2020 Nov 21.
Article
em En
| MEDLINE
| ID: mdl-33107872
ABSTRACT
A dipyrromethane-based germylene decorated with two phosphane groups has been used to prepare an unusual T-shaped palladium(0) containing a PGeP pincer germylene that acts as a Z-type ligand. This compound is a strong reducing reagent, as it has been easily oxidized to germyl-palladium(ii) derivatives with a gold(i) complex, HCl and Ph2S2 through processes that involve formal addition of a bond of the oxidant across the Ge-Pd bond.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Assunto da revista:
QUIMICA
Ano de publicação:
2020
Tipo de documento:
Article
País de afiliação:
Espanha