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Ambiphilicity of a mononuclear cobalt(III) superoxo complex.
Chen, Ting-Yi; Ho, Po-Hsun; Spyra, Can-Jerome; Meyer, Franc; Bill, Eckhard; Ye, Shengfa; Lee, Way-Zen.
Afiliação
  • Chen TY; Department of Chemistry, National Taiwan Normal University, Taipei 11677, Taiwan. wzlee@ntnu.edu.tw and Universität Göttingen, Institut für Anorganische Chemie, D-37077 Göttingen, Germany. franc.meyer@chemie.uni-goettingen.de.
  • Ho PH; Department of Chemistry, National Taiwan Normal University, Taipei 11677, Taiwan. wzlee@ntnu.edu.tw.
  • Spyra CJ; Universität Göttingen, Institut für Anorganische Chemie, D-37077 Göttingen, Germany. franc.meyer@chemie.uni-goettingen.de.
  • Meyer F; Universität Göttingen, Institut für Anorganische Chemie, D-37077 Göttingen, Germany. franc.meyer@chemie.uni-goettingen.de.
  • Bill E; Max-Planck-Institut für Chemische Energiekonversion, Mülheim an der Ruhr D-45470, Germany. eckhard.bill@cec.mpg.de.
  • Ye S; State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China. shengfa.ye@dicp.ac.cn and Max-Planck-Institut für Kohlenforschung, Mülheim an der Ruhr, D-45470, Germany. shengfa.ye@kofo.mpg.de.
  • Lee WZ; Department of Chemistry, National Taiwan Normal University, Taipei 11677, Taiwan. wzlee@ntnu.edu.tw and Department of Medicinal and Applied Chemistry, Kaohsiung Medical University, Kaohsiung 807, Taiwan.
Chem Commun (Camb) ; 56(94): 14821-14824, 2020 Nov 26.
Article em En | MEDLINE | ID: mdl-33151205
ABSTRACT
Addition of HOTf to a mixture of CoIII(BDPP)(O2˙) (1, H2BDPP = 2,6-bis((2-(S)-diphenylhydroxylmethyl-1-pyrrolidinyl)methyl)pyridine) and Cp*2Fe produced H2O2 in high yield implying formation of CoIII(BDPP)(OOH) (3), and reaction of Sc(OTf)3 with the same mixture gave a peroxo-bridged CoIII/ScIII5. These findings demonstrate the ambiphilic property of CoIII-superoxo 1.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2020 Tipo de documento: Article País de afiliação: Alemanha
Texto completo
Adicionar na Minha BVS
Imprimir
XML
PubMed Links
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2020 Tipo de documento: Article País de afiliação: Alemanha