Impact of Acidity Profile on Nascent Polyaniline in the Modified Rapid Mixing Process-Material Electrical Conductivity and Morphological Study.

ABSTRACT

Polyaniline (PANI) was synthesized chemically with the modified rapid mixing protocol in the presence of sulfuric acid of various concentrations. A two-step synthetic procedure was utilized maintaining low-temperature conditions. Application of the modified rapid mixing protocol allowed obtaining a material with local ordering. A higher concentration of acid allowed obtaining a higher yield of the reaction. Structural characterization performed with Fourier-transform infrared (FTIR) analysis showed the vibration bands characteristic of the formation of the emeraldine salt in both products. Ultraviolet-visible light (UV-Vis) spectroscopy was used for the polaronic band and the p-p* band determination. The absorption result served to estimate the average oxidation level of PANI by comparison of the ratio of the absorbance of the polaronic band to that of the π-π* transition. The absorbance ratio index was higher for PANI synthesized in a more acidic solution, which showed a higher doping level for this polymer. For final powder products, particle size distributions were also estimated, proving that PANI (5.0 M) is characterized by a larger number of small particles; however, these particles can more easily agglomerate and form larger structures. The X-ray diffraction (XRD) patterns revealed an equilibrium between the amorphous and semicrystalline phase in the doped PANI. A higher electrical conductivity value was measured for polymer synthesized in a higher acid concentration. The time-of-flight secondary ion mass spectrometry (TOF-SIMS) analysis showed that the molecular composition of the polymers was the same; hence, the difference in properties was a result of local ordering.