Global Diastereoconvergence in the Ireland-Claisen Rearrangement of Isomeric Enolates: Synthesis of Tetrasubstituted &#945;-Amino Acids.

Fulton, Tyler J; Cusumano, Alexander Q; Alexy, Eric J; Du, Yun E; Zhang, Haiming; Houk, K N; Stoltz, Brian M

Global Diastereoconvergence in the Ireland-Claisen Rearrangement of Isomeric Enolates: Synthesis of Tetrasubstituted α-Amino Acids.

Fulton, Tyler J; Cusumano, Alexander Q; Alexy, Eric J; Du, Yun E; Zhang, Haiming; Houk, K N; Stoltz, Brian M.

Afiliação

Fulton TJ; The Warren and Katharine Schlinger Laboratory for Chemistry and Chemical Engineering, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States.
Cusumano AQ; The Warren and Katharine Schlinger Laboratory for Chemistry and Chemical Engineering, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States.
Alexy EJ; The Warren and Katharine Schlinger Laboratory for Chemistry and Chemical Engineering, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States.
Du YE; The Warren and Katharine Schlinger Laboratory for Chemistry and Chemical Engineering, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States.
Zhang H; Small Molecule Process Chemistry, Genentech, Inc., South San Francisco, California 94080, United States.
Houk KN; Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095, United States.
Stoltz BM; The Warren and Katharine Schlinger Laboratory for Chemistry and Chemical Engineering, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States.

J Am Chem Soc ; 142(52): 21938-21947, 2020 12 30.

Article em En | MEDLINE | ID: mdl-33320668

Assuntos

Aminoácidos/química; Aminoácidos/síntese química; Alcenos/química; Técnicas de Química Sintética; Teoria da Densidade Funcional; Cetonas/química; Modelos Moleculares; Conformação Molecular; Estereoisomerismo

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Aminoácidos Idioma: En Revista: J Am Chem Soc Ano de publicação: 2020 Tipo de documento: Article País de afiliação: Estados Unidos País de publicação: Estados Unidos

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