Synthesis and reactivity of phosphine borohydride compounds.
Chem Commun (Camb)
; 57(3): 375-378, 2021 Jan 14.
Article
em En
| MEDLINE
| ID: mdl-33325466
ABSTRACT
Four lithium phosphine borohydride compounds featuring phenyl and naphthyl linkers have been synthesized. In-depth NMR analysis affords evidence for non-bonded through space P-B coupling. Reactivity towards CO2 leads to LiH transfer and to the quantitative formation of the corresponding ambiphilic phosphine-borane products.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Assunto da revista:
QUIMICA
Ano de publicação:
2021
Tipo de documento:
Article
País de afiliação:
França