Electron Redistribution within the Nitrogenase Active Site FeMo-Cofactor During Reductive Elimination of H<sub>2</sub> to Achieve N&#8801;N Triple-Bond Activation.

Lukoyanov, Dmitriy A; Yang, Zhi-Yong; Dean, Dennis R; Seefeldt, Lance C; Raugei, Simone; Hoffman, Brian M

Electron Redistribution within the Nitrogenase Active Site FeMo-Cofactor During Reductive Elimination of H₂ to Achieve N≡N Triple-Bond Activation.

Lukoyanov, Dmitriy A; Yang, Zhi-Yong; Dean, Dennis R; Seefeldt, Lance C; Raugei, Simone; Hoffman, Brian M.

Afiliação

Lukoyanov DA; Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States.
Yang ZY; Department of Chemistry and Biocemistry, Utah State University, Logan, Utah 84322, United States.
Dean DR; Department of Biochemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061, United States.
Seefeldt LC; Department of Chemistry and Biochemistry, Utah State University, Logan, Utah 84322, United States.
Raugei S; Pacific Northwest National Laboratory, Richland, Washington 99352, United States.
Hoffman BM; Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States.

J Am Chem Soc ; 142(52): 21679-21690, 2020 12 30.

Article em En | MEDLINE | ID: mdl-33326225

Assuntos

Hidrogênio/química; Molibdoferredoxina/química; Nitrogenase/química; Animais; Azotobacter vinelandii/enzimologia; Domínio Catalítico; Transporte de Elétrons

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Hidrogênio / Molibdoferredoxina / Nitrogenase Limite: Animals Idioma: En Revista: J Am Chem Soc Ano de publicação: 2020 Tipo de documento: Article País de afiliação: Estados Unidos País de publicação: Estados Unidos

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