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Synthesis of TEMPO radical decorated hollow porous aromatic frameworks for selective oxidation of alcohols.
Shen, Yan-Ming; Xue, Yun; Yan, Mi; Mao, Hui-Ling; Cheng, Hu; Chen, Zhuo; Sui, Zhi-Wei; Zhu, Shao-Bin; Yu, Xiu-Jun; Zhuang, Jin-Liang.
Afiliação
  • Shen YM; School of Chemistry and Materials Science, Key Lab for Functional Materials Chemistry of Guizhou Province, Guizhou Normal University, 116 Baoshan Road North, Guiyang 550001, P. R. China.
  • Xue Y; School of Chemistry and Materials Science, Key Lab for Functional Materials Chemistry of Guizhou Province, Guizhou Normal University, 116 Baoshan Road North, Guiyang 550001, P. R. China.
  • Yan M; School of Chemistry and Materials Science, Key Lab for Functional Materials Chemistry of Guizhou Province, Guizhou Normal University, 116 Baoshan Road North, Guiyang 550001, P. R. China.
  • Mao HL; School of Chemistry and Materials Science, Key Lab for Functional Materials Chemistry of Guizhou Province, Guizhou Normal University, 116 Baoshan Road North, Guiyang 550001, P. R. China.
  • Cheng H; School of Chemistry and Materials Science, Key Lab for Functional Materials Chemistry of Guizhou Province, Guizhou Normal University, 116 Baoshan Road North, Guiyang 550001, P. R. China.
  • Chen Z; School of Chemistry and Materials Science, Key Lab for Functional Materials Chemistry of Guizhou Province, Guizhou Normal University, 116 Baoshan Road North, Guiyang 550001, P. R. China.
  • Sui ZW; Center for Advanced Measurement Science, National Institute of Metrology, Beijing, China.
  • Zhu SB; NanoFCM INC., Xiamen Pioneering Park for Overseas Chinese Scholars, Xiamen, 361005, P. R. China. jlzhuang@xmu.edu.cn.
  • Yu XJ; School of Chemistry and Materials Science, Key Lab for Functional Materials Chemistry of Guizhou Province, Guizhou Normal University, 116 Baoshan Road North, Guiyang 550001, P. R. China and Institute for Inorganic and Analytical Chemistry, University of Frankfurt, Max-von-Laue-Strasse 7, 60438 Frank
  • Zhuang JL; School of Chemistry and Materials Science, Key Lab for Functional Materials Chemistry of Guizhou Province, Guizhou Normal University, 116 Baoshan Road North, Guiyang 550001, P. R. China and NanoFCM INC., Xiamen Pioneering Park for Overseas Chinese Scholars, Xiamen, 361005, P. R. China. jlzhuang@xmu.
Chem Commun (Camb) ; 57(7): 907-910, 2021 Jan 28.
Article em En | MEDLINE | ID: mdl-33393570
ABSTRACT
A bottom-up approach was developed to prepare TEMPO radical decorated hollow aromatic frameworks (HPAF-TEMPO) by using TEMPO radical functionalized monomers and SiO2 nanospheres as templates. The accessible inner layer, high density of TEMPO sites, and hybrid micro-/mesopores of the HPAF-TEMPO enable the aerobic oxidation of a broad range of alcohols with high efficiency and excellent selectivity.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2021 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2021 Tipo de documento: Article