Gram-Scale Synthesis of Cu(II)@COF via Solid-State Coordination Approach for Catalysis of Alkyne-Dihalomethane-Amine Coupling.
Inorg Chem
; 60(5): 3393-3400, 2021 Mar 01.
Article
em En
| MEDLINE
| ID: mdl-33595301
ABSTRACT
A novel covalent organic framework material COF-DM, which contains chelating coordination environments, was synthesized at the gram level under mild conditions. In addition, its Cu(II)-loaded complex of Cu(II)@COF-DM was prepared by impregnating COF-DM in an acetonitrile solution of CuCl2 via a solid-state coordination approach. The obtained Cu(II)-loaded Cu(II)@COF-DM can be used as a highly active heterogeneous catalyst to catalyze the alkyne-dihalomethane-amine coupling reactions.
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01-internacional
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MEDLINE
Idioma:
En
Revista:
Inorg Chem
Ano de publicação:
2021
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Article