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Synthesis and Photochemical Application of Hydrofluoroolefin (HFO) Based Fluoroalkyl Building Block.
Varga, Bálint; Tóth, Balázs L; Béke, Ferenc; Csenki, János T; Kotschy, András; Novák, Zoltán.
Afiliação
  • Varga B; ELTE "Lendület" Catalysis and Organic Synthesis Research Group, Institute of Chemistry, Eötvös Loránd University, Faculty of ́ Science, Pázmány Péter stny. 1/A, H-1117 Budapest, Hungary.
  • Tóth BL; ELTE "Lendület" Catalysis and Organic Synthesis Research Group, Institute of Chemistry, Eötvös Loránd University, Faculty of ́ Science, Pázmány Péter stny. 1/A, H-1117 Budapest, Hungary.
  • Béke F; ELTE "Lendület" Catalysis and Organic Synthesis Research Group, Institute of Chemistry, Eötvös Loránd University, Faculty of ́ Science, Pázmány Péter stny. 1/A, H-1117 Budapest, Hungary.
  • Csenki JT; ELTE "Lendület" Catalysis and Organic Synthesis Research Group, Institute of Chemistry, Eötvös Loránd University, Faculty of ́ Science, Pázmány Péter stny. 1/A, H-1117 Budapest, Hungary.
  • Kotschy A; Servier Research Institute of Medicinal Chemistry, Záhony u. 7.H-1031 Budapest, Hungary.
  • Novák Z; ELTE "Lendület" Catalysis and Organic Synthesis Research Group, Institute of Chemistry, Eötvös Loránd University, Faculty of ́ Science, Pázmány Péter stny. 1/A, H-1117 Budapest, Hungary.
Org Lett ; 23(12): 4925-4929, 2021 Jun 18.
Article em En | MEDLINE | ID: mdl-34097412
A novel fluoroalkyl iodide was synthesized on multigram scale from refrigerant gas HFO-1234yf as cheap industrial starting material in a simple, solvent-free, and easily scalable process. We demonstrated its applicability in a metal-free photocatalytic ATRA reaction to synthesize valuable fluoroalkylated vinyl iodides and proved the straightforward transformability of the products in cross-coupling chemistry to obtain conjugated systems.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Org Lett Assunto da revista: BIOQUIMICA Ano de publicação: 2021 Tipo de documento: Article País de afiliação: Hungria País de publicação: Estados Unidos
Texto completo
Adicionar na Minha BVS
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Org Lett Assunto da revista: BIOQUIMICA Ano de publicação: 2021 Tipo de documento: Article País de afiliação: Hungria País de publicação: Estados Unidos