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Intermetallic phases meet intermetalloid clusters.
Schütz, Max; Gemel, Christian; Klein, Wilhelm; Fischer, Roland A; Fässler, Thomas F.
Afiliação
  • Schütz M; Department of Chemistry, Technical University of Munich, Munich, Germany. thomas.faessler@lrz.tum.de roland.fischer@tum.de.
  • Gemel C; Department of Chemistry, Technical University of Munich, Munich, Germany. thomas.faessler@lrz.tum.de roland.fischer@tum.de.
  • Klein W; Department of Chemistry, Technical University of Munich, Munich, Germany. thomas.faessler@lrz.tum.de roland.fischer@tum.de.
  • Fischer RA; Department of Chemistry, Technical University of Munich, Munich, Germany. thomas.faessler@lrz.tum.de roland.fischer@tum.de.
  • Fässler TF; Department of Chemistry, Technical University of Munich, Munich, Germany. thomas.faessler@lrz.tum.de roland.fischer@tum.de.
Chem Soc Rev ; 50(15): 8496-8510, 2021 Aug 02.
Article em En | MEDLINE | ID: mdl-34114586
ABSTRACT
In this article intermetalloid clusters of Cu-Zn, Cu-AI, Cu-Sn, and Cu-Pb are discussed. Intermetallic compounds based on these metal combinations are of the Hume-Rothery type with well-defined structures related to the valence electron count of the involved metals. Many Zintl-type and molecular clusters with these metals are known with remarkable structural parallels to the respective solid-state phases. On several examples, this article discusses intermetalloid clusters in terms of their metal core structures and relates them to structural principles in intermetallic solid-state phases. Also the syntheses of such clusters are addressed. Zintl-type and molecular clusters are most generally accessible from organometallic precursor complexes with redox processes between the different metals as an underlying synthesis concept.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Soc Rev Ano de publicação: 2021 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Soc Rev Ano de publicação: 2021 Tipo de documento: Article
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