Constructing a triangular metallacycle with salen-Al and its application to a catalytic cyanosilylation reaction.
Chem Commun (Camb)
; 57(80): 10399-10402, 2021 Oct 07.
Article
em En
| MEDLINE
| ID: mdl-34542548
A triangular metallosalen-based metallacycle was constructed in quantitative yield by the self-assembly of a 180° bis(pyridyl)salen-Al complex and a 60° diplatinum(II) acceptor in a 1 : 1 stoichiometric ratio. This metallacycle was then successfully used to cyanosilylate a wide range of benzaldehydes with trimethylsilyl cyanide.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Assunto da revista:
QUIMICA
Ano de publicação:
2021
Tipo de documento:
Article
País de publicação:
Reino Unido