Synthesis of novel hexamolybdenum cluster-functionalized copper hydroxide nanocomposites and its catalytic activity for organic molecule degradation.
Sci Technol Adv Mater
; 22(1): 758-771, 2021.
Article
em En
| MEDLINE
| ID: mdl-34566493
ABSTRACT
A novel heterogeneous catalytic nanomaterial based on a molybdenum cluster-based halide (MC) and a single-layered copper hydroxynitrate (CHN) was first prepared by colloidal processing under ambient conditions. The results of the elemental composition and crystalline pattern indicated that CHN was comprehensively synthesized with the support of the MC compound. The absorbing characteristic in the ultraviolet and near-infrared regions was promoted by both of the ingredients. The proper chemical interaction between the materials is a crucial reason to modify the structure of the MCs and only a small decrease in the magnetic susceptibility of CHN. The heterogeneous catalytic activity of the obtained MC@CHN material was found to have a high efficiency and excellent reuse when it is activated by hydrogen peroxide (H2O2) for the degrading reaction of the organic pollutant at room temperature. A reasonable catalytic mechanism was proposed to explain the distinct role of the copper compound, Mo6 compound, and H2O2 in the production of the radical hydroxyl ion. This novel nanomaterial will be an environmentally promising candidate for dye removal.
10 Engineering and Structural materials; 102 Porous / Nanoporous / Nanostructured materials; 103 Composites; 105 Low-Dimension (1D/2D) materials; 204 Optics / Optical applications; 205 Catalyst / Photocatalyst / Photosynthesis; 301 Chemical syntheses / processing; 501 Chemical analyses; Molybdenum octahedral clusters; copper hydroxide nitrate; dye degradation; hydroxide peroxide; oxidation catalyst
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Sci Technol Adv Mater
Ano de publicação:
2021
Tipo de documento:
Article
País de afiliação:
Japão