Your browser doesn't support javascript.
loading
Filled trivacant icosahedra as building fragments in 17-atom endohedral germanides [TM2@Ge17]n- (TM = Co, Ni).
Wallach, Christoph; Selic, Yasmin; Witzel, Benedikt J L; Klein, Wilhelm; Fässler, Thomas F.
Afiliação
  • Wallach C; Department Chemie, Technische Universität München, Lichtenbergstraße 4, 85748 Garching b. München, Germany. thomas.faessler@lrz.tum.de.
  • Selic Y; Department Chemie, Technische Universität München, Lichtenbergstraße 4, 85748 Garching b. München, Germany. thomas.faessler@lrz.tum.de.
  • Witzel BJL; Department Chemie, Technische Universität München, Lichtenbergstraße 4, 85748 Garching b. München, Germany. thomas.faessler@lrz.tum.de.
  • Klein W; Department Chemie, Technische Universität München, Lichtenbergstraße 4, 85748 Garching b. München, Germany. thomas.faessler@lrz.tum.de.
  • Fässler TF; Department Chemie, Technische Universität München, Lichtenbergstraße 4, 85748 Garching b. München, Germany. thomas.faessler@lrz.tum.de.
Dalton Trans ; 50(39): 13671-13675, 2021 Oct 12.
Article em En | MEDLINE | ID: mdl-34570145
ABSTRACT
The syntheses and the characterization of two 17-atom endohedral Ge clusters, [Co2@Ge17]6- (1a) and [Ni2@Ge17]4- (2a), are reported. The anions 1a and 2a, which close the gap between the known 16- and 18-atom Ge clusters, are investigated by single crystal X-ray diffraction and by quantum chemical calculations. The structures mark a new example on the pathway for cluster growth towards larger clusters with icosahedral symmetry. Furthermore, the [Co@Ge10]3- anion (3a) is obtained from liquid ammonia.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Dalton Trans Assunto da revista: QUIMICA Ano de publicação: 2021 Tipo de documento: Article País de afiliação: Alemanha

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Dalton Trans Assunto da revista: QUIMICA Ano de publicação: 2021 Tipo de documento: Article País de afiliação: Alemanha
...