Iterative step-growth synthesis and degradation of unimolecular polyviologens under mild conditions.

Delawder, Abigail O; Palmquist, Mark S; Dorsainvil, Jovelt M; Colley, Nathan D; Saak, Tiana M; Gruschka, Max C; Li, Xuesong; Li, Lei; Zhang, Yipei; Barnes, Jonathan C

Delawder, Abigail O; Palmquist, Mark S; Dorsainvil, Jovelt M; Colley, Nathan D; Saak, Tiana M; Gruschka, Max C; Li, Xuesong; Li, Lei; Zhang, Yipei; Barnes, Jonathan C.

Afiliação

Delawder AO; Department of Chemistry, Washington University in St. Louis, St. Louis, MO 63130, USA. jcbarnes@wustl.edu.
Palmquist MS; Department of Chemistry, Washington University in St. Louis, St. Louis, MO 63130, USA. jcbarnes@wustl.edu.
Dorsainvil JM; Department of Chemistry, Washington University in St. Louis, St. Louis, MO 63130, USA. jcbarnes@wustl.edu.
Colley ND; Department of Chemistry, Washington University in St. Louis, St. Louis, MO 63130, USA. jcbarnes@wustl.edu.
Saak TM; Department of Chemistry, Washington University in St. Louis, St. Louis, MO 63130, USA. jcbarnes@wustl.edu.
Gruschka MC; Department of Chemistry, Washington University in St. Louis, St. Louis, MO 63130, USA. jcbarnes@wustl.edu.
Li X; Department of Chemistry, Washington University in St. Louis, St. Louis, MO 63130, USA. jcbarnes@wustl.edu.
Li L; Department of Chemistry, Washington University in St. Louis, St. Louis, MO 63130, USA. jcbarnes@wustl.edu.
Zhang Y; Department of Chemistry, Washington University in St. Louis, St. Louis, MO 63130, USA. jcbarnes@wustl.edu.
Barnes JC; Department of Chemistry, Washington University in St. Louis, St. Louis, MO 63130, USA. jcbarnes@wustl.edu.

Chem Commun (Camb) ; 58(9): 1358-1361, 2022 Jan 27.

Article em En | MEDLINE | ID: mdl-34989373

ABSTRACT

ABSTRACT

An iterative step-growth addition method was used to expedite the gram-scale synthesis of main-chain polyviologens by several days, while also producing the longest main-chain polyviologen (i.e., 26 viologen subunits) reported to date. Facile degradation using inorganic and organic aqueous bases was also demonstrated for a representative oligoviologen (6V-Me·12Cl), a polyviologen (26V-Me·52Cl), and oligoviologen-crosslinked hydrogels.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2022 Tipo de documento: Article País de afiliação: Estados Unidos

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