The Divergent Reactivity of Lactones Derived from Butadiene and Carbon Dioxide in Macromolecular Synthesis.
Macromol Rapid Commun
; 44(1): e2200348, 2023 Jan.
Article
em En
| MEDLINE
| ID: mdl-35856259
ABSTRACT
The catalytic conversion of carbon dioxide and 1,3-butadiene into unsaturated lactone monomers provides an efficient route for converting sustainable carbon feedstocks into novel macromolecules. The chemical reactivity of this monomer is reviewed in order to highlight the many viable mechanistic pathways. Polymerization strategies, monomer alterations, and post-polymerization modifications are covered. The polymerization methods include radical, coordination, conjugate addition, ring-opening, olefin metathesis, and thiol-ene chemistries. Materials derived from these processes possess a wide range of function including responsiveness, degradability, adhesion, recyclability, and self-assembly. These aspects along with the advances in polymer chemistry that make them possible are discussed, along with a perspective on the future directions of the field.
Palavras-chave
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Butadienos
/
Dióxido de Carbono
Idioma:
En
Revista:
Macromol Rapid Commun
Ano de publicação:
2023
Tipo de documento:
Article
País de afiliação:
Estados Unidos