Distinct Reactivity Modes of a Copper Hydride Enabled by an Intramolecular Lewis Acid.
J Am Chem Soc
; 144(33): 15038-15046, 2022 08 24.
Article
em En
| MEDLINE
| ID: mdl-35960993
ABSTRACT
We disclose a 1,4,7-triazacyclononane (TACN) ligand featuring an appended boron Lewis acid. Metalation with Cu(I) affords a series of tetrahedral complexes including a boron-capped cuprous hydride. We demonstrate distinct reactivity modes as a function of chemical oxidation hydride transfer to CO2 in the copper(I) state and oxidant-induced H2 evolution as well as alkyne reduction.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Cobre
/
Ácidos de Lewis
Idioma:
En
Revista:
J Am Chem Soc
Ano de publicação:
2022
Tipo de documento:
Article
País de afiliação:
Estados Unidos