Water-soluble Self-assembled {Pd84 }Ac Polyoxopalladate Nano-wheel as a Supramolecular Host.
Angew Chem Int Ed Engl
; 62(1): e202214203, 2023 01 02.
Article
em En
| MEDLINE
| ID: mdl-36336660
ABSTRACT
Polyoxopalladates (POPs) are a class of self-assembling palladium-oxide clusters that span a variety of sizes, shapes and compositions. The largest of this family, {Pd84 }Ac , is constructed from 14 building units of {Pd6 } and lined on the inner and outer torus by 28 acetate ligands. Due to its high water solubility, large hydrophobic cavity and distinct 1 Hâ
NMR fingerprint {Pd84 }Ac is an ideal molecule for exploring supramolecular behaviour with small organic molecules in aqueous media. Molecular visualisation studies highlighted potential binding sites between {Pd84 }Ac and these species. Nuclear Magnetic Resonance (NMR) techniques, including 1 Hâ
NMR, 1 H Diffusion Ordered Spectroscopy (DOSY) and Nuclear Overhauser Spectroscopy (NOESY), were employed to study the supramolecular chemistry of this system. Here, we provide conclusive evidence that {Pd84 }Ac forms a 1 7 host-guest complex with benzyl viologen (BV2+ ) in aqueous solution.
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01-internacional
Base de dados:
MEDLINE
Assunto principal:
Água
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Ano de publicação:
2023
Tipo de documento:
Article
País de afiliação:
Reino Unido