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Construction of diverse polycyclic N-heterocycles via cascade allylic amination/Diels-Alder reaction.
Yang, Zhenkun; Xie, Hongling; Tang, Luning; Sun, Jianwei; Han, Zhengyu; Huang, Hai.
Afiliação
  • Yang Z; Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, School of Petrochemical Engineering, Changzhou University, Changzhou, China. huanghai@cczu.edu.cn.
  • Xie H; Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, School of Petrochemical Engineering, Changzhou University, Changzhou, China. huanghai@cczu.edu.cn.
  • Tang L; Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, School of Petrochemical Engineering, Changzhou University, Changzhou, China. huanghai@cczu.edu.cn.
  • Sun J; Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, School of Petrochemical Engineering, Changzhou University, Changzhou, China. huanghai@cczu.edu.cn.
  • Han Z; Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong SAR, China.
  • Huang H; Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, School of Petrochemical Engineering, Changzhou University, Changzhou, China. huanghai@cczu.edu.cn.
Chem Commun (Camb) ; 58(95): 13258-13261, 2022 Nov 29.
Article em En | MEDLINE | ID: mdl-36367142
ABSTRACT
An efficient cascade approach for the construction of nitrogen-containing polycyclic compounds from amines tethered with an alkenyl (or alkynyl) group and divinyl carbonates is described. In the presence of Pd(0)-catalyst, an active zwitterionic allylpalladium species is generated and undergoes allylic amination with various amines followed by Diels-Alder reaction to form various polycyclic N-heterocyclic products, including hydrophenanthridines, hydrobenzo[c]azepines (hydro)isoindoles and hydrobenzo[cd]indoles.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Aminas Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2022 Tipo de documento: Article País de afiliação: China
Texto completo
Adicionar na Minha BVS
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Aminas Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2022 Tipo de documento: Article País de afiliação: China