Triel Bonds with Au Atoms as Electron Donors.
Chemphyschem
; 24(6): e202200748, 2023 Mar 14.
Article
em En
| MEDLINE
| ID: mdl-36448371
ABSTRACT
The novel triel bonds of BX3 (X=H, F, Cl, Br, and I) and C5 H5 B as electron acceptors and AuR2 (R=Cl and CH3 ) as an electron donor were explored. The triel bond is a primary driving force for most complexes, while the contribution from a halogen-chlorine interaction in BX3 -AuCl2 (X=Cl, Br, and I) and an iodine-Au interaction in BI3 -Au(CH3 )3 is also very important. Interestingly, the positively charged Au atom of AuCl2 can attractively bind with the holes of BX3 and C5 H5 B. The interaction energy lies in the range of 1 and 80â
kcal/mol, in the order X=F
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chemphyschem
Assunto da revista:
BIOFISICA
/
QUIMICA
Ano de publicação:
2023
Tipo de documento:
Article
País de afiliação:
China