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N-Allylbenzimidazole as a strategic surrogate in Rh-catalyzed stereoselective trans-propenylation of aryl C(sp2)-H bond.
Biswal, Pragati; Nanda, Tanmayee; Banjare, Shyam Kumar; Mohanty, Smruti Ranjan; Mishra, Ranjit; Ravikumar, Ponneri C.
Afiliação
  • Biswal P; School of Chemical Sciences, National Institute of Science Education and Research (NISER) Bhubaneswar, Jatni, Odisha 752050, India. pcr@niser.ac.in.
  • Nanda T; Homi Bhabha National Institute (HBNI), Training School Complex, Anushaktinagar, Mumbai, 400094, India.
  • Banjare SK; School of Chemical Sciences, National Institute of Science Education and Research (NISER) Bhubaneswar, Jatni, Odisha 752050, India. pcr@niser.ac.in.
  • Mohanty SR; Homi Bhabha National Institute (HBNI), Training School Complex, Anushaktinagar, Mumbai, 400094, India.
  • Mishra R; School of Chemical Sciences, National Institute of Science Education and Research (NISER) Bhubaneswar, Jatni, Odisha 752050, India. pcr@niser.ac.in.
  • Ravikumar PC; Homi Bhabha National Institute (HBNI), Training School Complex, Anushaktinagar, Mumbai, 400094, India.
Chem Commun (Camb) ; 59(2): 199-202, 2022 Dec 22.
Article em En | MEDLINE | ID: mdl-36476727
ABSTRACT
A Rh-catalyzed C(sp2)-H propenylation has been reported by taking N-allyl benzimidazole as an allylamine congener. This transformation has been observed for the first time, where a tandem process of C-H allylation followed by alkene isomerization delivers a highly stereoselective trans-propenylated product. Detailed mechanistic studies including the characterization of rhodacycle-intermediates have been conducted to understand the mechanism.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Ródio / Alilamina Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2022 Tipo de documento: Article País de afiliação: Índia
Texto completo
Adicionar na Minha BVS
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Ródio / Alilamina Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2022 Tipo de documento: Article País de afiliação: Índia