Structurally Ordered PtNi Intermetallic Nanoparticles as Efficient and Stable Cathode Catalysts for Proton Exchange Membrane Fuel Cells.

ABSTRACT

Exploring oxygen reduction reaction (ORR) catalysts with superior electrochemical performance and long-term stability is crucial to the development of proton exchange membrane fuel cells (PEMFCs). In this work, graphited carbon with high specific surface area was obtained under relatively low temperature using Ni catalyst, then ordered nanoparticles (NPs) PtNi catalysts attaching to graphited carbon were synthesized via polyol reduction and thermal treatment. Benefiting from graphitized carbon support and appropriate order degree, PtNi/GC-700 NPs catalyst exhibits excellent electrocatalytic ORR performance with specific and mass activities as high as 2.8-fold and 3.7-fold of the commercial Pt/C catalyst, respectively. Besides, the as-prepared PtNi/GC-700 catalyst exhibits superior stability with negligible degradation after 10000 potential cycles, due to its ordered chemical structure. The work described herein highlights the potential of structurally ordered electrocatalysts for efficient and durable fuel cell cathodic catalysts.