Manganese(I)-Catalyzed Asymmetric Hydrophosphination of &#945;,ß-Unsaturated Carbonyl Derivatives.

Postolache, Roxana; Pérez, Juana M; Castiñeira Reis, Marta; Ge, Luo; Sinnema, Esther G; Harutyunyan, Syuzanna R

Manganese(I)-Catalyzed Asymmetric Hydrophosphination of α,ß-Unsaturated Carbonyl Derivatives.

Postolache, Roxana; Pérez, Juana M; Castiñeira Reis, Marta; Ge, Luo; Sinnema, Esther G; Harutyunyan, Syuzanna R.

Afiliação

Postolache R; Stratingh Institute for Chemistry, University of Groningen, 9747 AG Groningen, The Netherlands.
Pérez JM; Stratingh Institute for Chemistry, University of Groningen, 9747 AG Groningen, The Netherlands.
Castiñeira Reis M; Stratingh Institute for Chemistry, University of Groningen, 9747 AG Groningen, The Netherlands.
Ge L; Stratingh Institute for Chemistry, University of Groningen, 9747 AG Groningen, The Netherlands.
Sinnema EG; Stratingh Institute for Chemistry, University of Groningen, 9747 AG Groningen, The Netherlands.
Harutyunyan SR; Stratingh Institute for Chemistry, University of Groningen, 9747 AG Groningen, The Netherlands.

Org Lett ; 25(10): 1611-1615, 2023 Mar 17.

Article em En | MEDLINE | ID: mdl-36892214

ABSTRACT

ABSTRACT

Here we report catalytic asymmetric hydrophosphination of α,ß-unsaturated carbonyl derivatives using a chiral Mn(I) complex as a catalyst. Through H-P bond activation, various phosphine-containing chiral products can be accessed via hydrophosphination of various ketone-, ester-, and carboxamide-based Michael acceptors.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Org Lett Assunto da revista: BIOQUIMICA Ano de publicação: 2023 Tipo de documento: Article País de afiliação: Holanda

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