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[Ga@Bi10(NbMes)2]3-: a linear Nb-GaI-Nb filament coordinated by a bismuth cage.
Qiao, Lei; Yang, Tao; Frenking, Gernot; Sun, Zhong-Ming.
Afiliação
  • Qiao L; State Key Laboratory of Element-Organic Chemistry, Tianjin Key Lab for Institution Rare Earth Materials and Applications, School of Materials Science and Engineering, Nankai University, Tianjin 300350, Tianjin, China. sunlab@nankai.edu.cn.
  • Yang T; MOE Key Laboratory for Non-Equilibrium Synthesis and Modulation of Condensed Matter, School of Physics, Xi'an Jiaotong University, Xi'an 710049, Shaanxi, China. taoyang1@xjtu.edu.cn.
  • Frenking G; Donostia International Physics Center (DIPC), P.K. 1072, Donostia 20080, Euskadi, Spain.
  • Sun ZM; Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse 4, Marburg 35043, Germany.
Chem Commun (Camb) ; 59(27): 4024-4027, 2023 Mar 30.
Article em En | MEDLINE | ID: mdl-36920786
ABSTRACT
In this work, we report a low-valent Ga(I) complex, [Ga@Bi10(NbMes)2]3-, with a linear Nb-Ga-Nb fragment, representing the first compound with Nb-Ga and Nb-Bi bonds. Quantum-chemical calculations reveal that the complex is an electron-precise cluster. The possible fragmentation pathway of the title cluster was studied by using electrospray ionization mass spectrometry and theoretical calculations.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2023 Tipo de documento: Article País de afiliação: China
Texto completo
Adicionar na Minha BVS
Imprimir
XML
PubMed Links
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2023 Tipo de documento: Article País de afiliação: China