Crystal structure of bis-[4-(all-yloxy)-N'-(but-2-en-1-yl-idene)benzohydrazidato]nickel(II).
Acta Crystallogr E Crystallogr Commun
; 79(Pt 5): 465-468, 2023 Apr 01.
Article
em En
| MEDLINE
| ID: mdl-37151832
ABSTRACT
In the title complex, [Ni(C14H15N2O2)2], the nickel(II) atom exhibits a square-planar coordination geometry, being coordinated by two negatively charged N,O chelating ligands in a trans configuration, with the metal located on a crystallographic center of symmetry. The X-ray structural characterization showed the complex to be disordered over two orientations with refined occupancies of 0.898â
(2) and 0.102â
(2). The whole mol-ecule is close to planar, the five- and six-membered rings subtending a dihedral angle of 7.5â
(2)°. The crystal packing is supported by C-Hâ¯π and C-Hâ¯O inter-actions that form a di-periodic layered network.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr E Crystallogr Commun
Ano de publicação:
2023
Tipo de documento:
Article
País de afiliação:
Bangladesh