Palladium-catalyzed disilylation of ortho-halophenylethylenes enabled by 2-pyridone ligand.
Chem Commun (Camb)
; 59(39): 5922-5925, 2023 May 11.
Article
em En
| MEDLINE
| ID: mdl-37171020
A palladium-catalyzed disilylation reaction applicable for a variety of non-, α-, or ß-substituted and α,ß-disubstituted ortho-halophenylethylenes has been developed. This reaction proceeds with high yields and very low catalyst loadings. The two C-Si bonds of the disilylated products could be well-differentiated chemoselectively in the reaction with various electrophiles.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Assunto da revista:
QUIMICA
Ano de publicação:
2023
Tipo de documento:
Article
País de afiliação:
China
País de publicação:
Reino Unido