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Conversion of 5-hydroxymethylfurfural to furan-2,5-dicarboxylic acid by a simple and metal-free catalytic system.
Wang, Xue; Guo, Xinyuan; Wang, Xinmei; Li, Chi; Wang, Shanjun; Li, Han; Gao, Yan'an; Li, Yiying; Wang, Jinhui; Xu, Huanjun.
Afiliação
  • Wang X; Department of Medicinal Chemistry and Natural Medicine Chemistry, College of Pharmacy, Harbin Medical University Harbin China 15798946232@163.com.
  • Guo X; School of Science, Qiongtai Normal University Haikou 571127 China.
  • Wang X; School of Science, Qiongtai Normal University Haikou 571127 China.
  • Li C; School of Science, Qiongtai Normal University Haikou 571127 China.
  • Wang S; School of Science, Qiongtai Normal University Haikou 571127 China.
  • Li H; School of Science, Qiongtai Normal University Haikou 571127 China.
  • Gao Y; Key Laboratory of Ministry of Education for Advanced Materials in Tropical, Island Resources, Hainan University Haikou 570228 China.
  • Li Y; College of Basic Medicine and Life Sciences, Hainan Medical University Haikou China.
  • Wang J; Department of Medicinal Chemistry and Natural Medicine Chemistry, College of Pharmacy, Harbin Medical University Harbin China 15798946232@163.com.
  • Xu H; Key Laboratory of Child Cognition and Behavior Development of Hainan Province, Qiongtai Normal University Haikou China.
RSC Adv ; 13(20): 13819-13823, 2023 May 02.
Article em En | MEDLINE | ID: mdl-37181510
ABSTRACT
A simple and metal-free catalytic system composed of NaOtBu/DMF and an O2 balloon efficiently converted 5-hydroxymethylfurfural (5-HMF) to furan-2,5-dicarboxylic acid with an 80.85% yield. 5-HMF analogues and various types of alcohols were also transformed to their corresponding acids in satisfactory to excellent yield by this catalytic system.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: RSC Adv Ano de publicação: 2023 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: RSC Adv Ano de publicação: 2023 Tipo de documento: Article