Core-shell FeCo@carbon nanocages encapsulated in biomass-derived carbon aerogel: Architecture design and interface engineering of lightweight, anti-corrosion and superior microwave absorption.

ABSTRACT

The development of multifunctional microwave absorbing materials for practical applications in complex environments is a challenging research hotspot. Herein, the core-shell structure FeCo@C nanocages were successfully anchored on the surface of biomass-derived carbon (BDC) from pleurotus eryngii (PE) via freeze-drying and electrostatic self-assembly process, achieving lightweight, anti-corrosive, and excellent absorption properties. The superior versatility benefits from the large specific surface area, high conductivity, three-dimensional cross-linked networks, and appropriate impedance matching characteristics. The as-prepared aerogel realizes a minimum reflection loss (RLmin) of -69.5 dB with a corresponding effective absorption bandwidth (EAB) of 8.6 GHz at 2.9 mm. Simultaneously, the computer simulation technique (CST) further proves that the multifunctional material can dissipate microwave energy in actual applications. More importantly, the special heterostructure of aerogel endows excellent resistance to acid, alkali, salt medium, allowing potential applications of the microwave absorbing materials under complex environmental conditions.