Your browser doesn't support javascript.
loading
Applying Machine Learning to investigate metal isotope variations at the watershed scale: A case study with lithium isotopes across the Yukon River Basin.
Cotroneo, Sarina; Kang, Myunghak; Clark, Ian D; Bataille, Clément P.
Afiliação
  • Cotroneo S; 25 Templeton Street, Department of Earth and Environmental Sciences, University of Ottawa, Ottawa, ON K1N 6N5, Canada. Electronic address: sarina.cotroneo@uottawa.ca.
  • Kang M; 25 Templeton Street, Department of Earth and Environmental Sciences, University of Ottawa, Ottawa, ON K1N 6N5, Canada.
  • Clark ID; 25 Templeton Street, Department of Earth and Environmental Sciences, University of Ottawa, Ottawa, ON K1N 6N5, Canada.
  • Bataille CP; 25 Templeton Street, Department of Earth and Environmental Sciences, University of Ottawa, Ottawa, ON K1N 6N5, Canada.
Sci Total Environ ; 896: 165165, 2023 Oct 20.
Article em En | MEDLINE | ID: mdl-37394077
Constraining the multiple climatic, lithological, topographic, and geochemical variables controlling isotope variations in large rivers is often challenging with standard statistical methods. Machine learning (ML) is an efficient method for analyzing multidimensional datasets, resolving correlated processes, and exploring relationships between variables simultaneously. We tested four ML algorithms to elucidate the controls of riverine δ7Li variations across the Yukon River Basin (YRB). We compiled (n = 102) and analyzed new samples (n = 21), producing a dataset of 123 river water samples collected across the basin during the summer including δ7Li and extracted environmental, climatological, and geological characteristics of the drainage area for each sample from open-access geospatial databases. The ML models were trained, tuned, and tested under multiple scenarios to avoid issues such as overfitting. Random Forests (RF) performed best at predicting δ7Li across the basin, with the median model explaining 62 % of the variance. The most important variables controlling δ7Li across the basin are elevation, lithology, and past glacial coverage, which ultimately influence weathering congruence. Riverine δ7Li has a negative dependence on elevation. This reflects congruent weathering in kinetically-limited mountain zones with short residence times. The consistent ranking of lithology, specifically igneous and metamorphic rock cover, as a top feature controlling riverine δ7Li modeled by the RFs is unexpected. Further study is required to validate this finding. Rivers draining areas that were extensively covered during the last glacial maximum tend to have lower δ7Li due to immature weathering profiles resulting in short residence times, less secondary mineral formation and therefore more congruent weathering. We demonstrate that ML provides a fast, simple, visualizable, and interpretable approach for disentangling key controls of isotope variations in river water. We assert that ML should become a routine tool, and present a framework for applying ML to analyze spatial metal isotope data at the catchment scale.
Palavras-chave

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Tipo de estudo: Prognostic_studies Idioma: En Revista: Sci Total Environ Ano de publicação: 2023 Tipo de documento: Article País de publicação: Holanda

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Tipo de estudo: Prognostic_studies Idioma: En Revista: Sci Total Environ Ano de publicação: 2023 Tipo de documento: Article País de publicação: Holanda