Blue-Light Driven Iron-Catalyzed Oxy-phosphinylation of Activated Alkenes for ß-Ketophosphine Oxide Synthesis.
Chemistry
; 29(69): e202302358, 2023 Dec 11.
Article
em En
| MEDLINE
| ID: mdl-37681747
ABSTRACT
We have developed an original blue-light mediated iron-catalyzed oxy-phosphinylation of activated alkenes by secondary phosphine oxides under air at room temperature. Various ß-ketophosphine oxides were then obtained in 43-97 % isolated yields. Control experiments revealed that radical process is involved in the mechanism.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chemistry
Assunto da revista:
QUIMICA
Ano de publicação:
2023
Tipo de documento:
Article
País de afiliação:
França