Superhydrophobic MOFs with enhanced catalytic activity for chemical fixation of CO2.
Dalton Trans
; 52(40): 14319-14323, 2023 Oct 17.
Article
em En
| MEDLINE
| ID: mdl-37791918
ABSTRACT
A general approach to prepare superhydrophobic MOFs (denoted as MOFs-CF3) through a post-decorating strategy for highly efficient chemical fixation of CO2 was demonstrated. The enhanced catalytic activity of MOFs-CF3 is attributed to a synergistic effect between the Lewis acid sites of MOFs and modification of the electron-withdrawing trifluoromethyl group, which resulted in a high CO2 enrichment capacity. The possible mechanism of cycloaddition catalyzed by the MOFs-CF3 catalyst was also proposed.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Dalton Trans
Assunto da revista:
QUIMICA
Ano de publicação:
2023
Tipo de documento:
Article