Molybdenum disulfide nanoflowers - doped sodium alginate/polyvinyl alcohol porous xerogel for methylene blue and copper ion adsorption.

ABSTRACT

In order to improve the adsorption performance of MoS2, as well as to solve the problems of MoS2-powder in adsorption, which is prone to agglomeration and difficulty to be recycled, we prepared MoS2-nanoflowers(MoS2-NFs), and mixed them with sodium alginate/polyvinyl alcohol(SA/PVA) to prepare MoS2-NFs/SA/PVA xerogel(MSP) by freezing-lyophilization. Then two forms of xerogels - block-MSP(MSPB) and spherical-MSP(MSPS) were prepared, and they were used as methylene blue(MB) and Cu2+ adsorbent. It was found that MoS2-NFs were evenly dispersed inside the SA/PVA with no agglomeration, while the interior of MSPB/MSPS showed the structure of parallel-pores and radial-pores, respectively. The adsorption capacity of MSPB/MSPS on MB can reach 233 mg/g, which is five times higher than SA/PVA-gel, showing excellent synergistic-adsorption effect, and the adsorption capacity for Cu2+ reaches 271 mg/g. The adsorption mechanism indicated that the adsorption of MB by MSPB/MSPS conformed to pseudo-first-order model, with electrostatic force as the main force. And their adsorption of Cu2+ conformed to pseudo-second-order model and was dominated by Lewis acid/base soft-soft interactions. Notably, after long-term adsorption, MSPB/MSPS maintains its shape and more than 90 % of the adsorption capacity, ensuring the recovery and reuse of materials. So, MSPB/MSPS has great potential in adsorption, providing a new solution for sewage purification.