NaBr-Assisted Sintering of Na3Zr2Si2PO12 Ceramic Electrolyte Stabilizes a Rechargeable Solid-state Sodium Metal Battery.
ACS Appl Mater Interfaces
; 15(42): 49321-49328, 2023 Oct 25.
Article
em En
| MEDLINE
| ID: mdl-37847183
ABSTRACT
Solid-state metal batteries with nonflammable solid-state electrolytes are regarded as the next generation of energy storage technology on account of their high safety and energy density. However, as for most solid electrolytes, low room temperature ionic conductivity and interfacial issues hinder their practical application. In this work, Na super ionic conductor (NASICON)-type Na3Zr2Si2PO12 (NZSP) electrolytes with improved ionic conductivity are synthesized by the NaBr-assisted sintering method. The effects of the NaBr sintering aid on the crystalline phase, microstructure, densification degree, and electrical performance as well as the electrochemical performances of the NZSP ceramic electrolyte are investigated in detail. Specifically, the NZSP-7%NaBr-1150 ceramic electrolyte has an ionic conductivity of 1.2 × 10-3 S cm-1 (at 25 °C) together with an activation energy of 0.28 eV. A low interfacial resistance of 35 Ω cm2 is achieved with the Na/NZSP-7%NaBr-1150 interface. Furthermore, the Na/NZSP-7%NaBr-1150/Na3V2(PO4)3 battery manifests excellent cycling stability with a capacity retention of 98% after 400 cycles at 1 C and 25 °C.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
ACS Appl Mater Interfaces
Assunto da revista:
BIOTECNOLOGIA
/
ENGENHARIA BIOMEDICA
Ano de publicação:
2023
Tipo de documento:
Article