Overlooked Promising Green Features of Electrospun Cellulose-Based Fibers in Lithium-Ion Batteries.

ABSTRACT

Lithium-ion batteries (LIBs) are accounted as promising power tools, applicable in a wide range of energy-based equipment, from portable devices to electric vehicles. Meanwhile, approaching a cost-effective, environmentally friendly, and safe LIB array has remained sluggish yet. In this regard, cellulose, as a nontoxic natural renewable polymer, has provided a stable and cohesive electrode structure with excellent mechanical stability and reduced electrode cracking or delamination during cycling. Additionally, the porous configuration of the cellulose allows for efficient and faster ion transport as a separator component. Miniaturizing cellulose and its derivatives have revealed more fabulous characteristics for the anode, cathode, and separator resulting from the increased surface-to-volume ratio and superior porosity, as well as their thin and lightweight architectures. The focal point of this review outlines the challenges relating to the extraction and electrospinning of cellulose-based nanofibers. Additionally, the efforts to employ these membranes as the LIBs' components are elucidated. Correspondingly, despite the great performance of cellulose-based LIB structures, a research gap is sensed in this era, possibly due to the difficulties in processing the electrospun cellulose fibers. Hence, this review can provide a source of recent advancements and innovations in cellulose-based electrospun LIBs for researchers who aim to develop versatile battery structures using green materials, worthwhile, and eco-friendly processing techniques.