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At the limits of bisphosphonio-substituted stannylenes.
Nasemann, Sina; Franz, Roman; Kargin, Denis; Bruhn, Clemens; Kelemen, Zsolt; Gutmann, Torsten; Pietschnig, Rudolf.
Afiliação
  • Nasemann S; Department of Chemistry, University of Kassel, Heinrich-Plett-Str. 40, 34132, Kassel, Germany.
  • Franz R; Department of Chemistry, University of Kassel, Heinrich-Plett-Str. 40, 34132, Kassel, Germany.
  • Kargin D; Department of Chemistry, University of Kassel, Heinrich-Plett-Str. 40, 34132, Kassel, Germany.
  • Bruhn C; Department of Chemistry, University of Kassel, Heinrich-Plett-Str. 40, 34132, Kassel, Germany.
  • Kelemen Z; Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, Muegyetem Rkp. 3, H-1111, Budapest, Hungary.
  • Gutmann T; Eduard Zintl Institute for Inorganic and Physical Chemistry, Technical University of Darmstadt, Peter-Grünberg-Straße 8, 64287, Darmstadt, Germany.
  • Pietschnig R; Department of Chemistry, University of Kassel, Heinrich-Plett-Str. 40, 34132, Kassel, Germany.
Chem Asian J ; : e202300950, 2023 Dec 13.
Article em En | MEDLINE | ID: mdl-38091243
ABSTRACT
Donor stabilization of Sn(II) and Pb(II) halides with 1,1'-ferrocenylene bridged bisphosphanes has been explored for Fe(C5 H4 P(C6 H5 )2 )2 (dppf), and Fe(C5 H4 PH(C4 H9 ))2 . These bisphosphanes are reacted with SnBr2 and PbCl2 with and without additional Lewis acid (AlCl3 ) forming acyclic and cyclic donor adducts from which the latter represent bisphosphoniotetrylenes. Since dynamic exchange in solution is observed, characterization includes solution and solid-state NMR in addition to SC-XRD, amended by DFT calculations.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Asian J Ano de publicação: 2023 Tipo de documento: Article País de afiliação: Alemanha
Texto completo
Adicionar na Minha BVS
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XML
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Asian J Ano de publicação: 2023 Tipo de documento: Article País de afiliação: Alemanha