Surface activity, mechanisms, kinetics, and thermodynamic study of adsorption of malachite green dye onto sulfuric acid-functionalized Moringa oleifera leaves from aqueous solution.

ABSTRACT

In the present study, activated carbon prepared from H2SO4-functionalized Moringa oleifera leaves (ACMOL) was used as a potential adsorbent for the effective removal of malachite green (MG) dye from aqueous media. FT-IR, SEM, EDS, Zeta potential, XRD, BET, proximate, and CHNS analysis techniques were used for surface characterization of the ACMOL. The adsorption efficiency of the ACMOL was investigated as a function of varying adsorbent dosage (0.02-0.2 g/100 mL), pH (3.0-9.0), ionic strength (0.1-0.5 M KCl), urea concentration (0.1-0.5 M), contact time (30-210 min), and temperature (303-323 K). The representative adsorption isotherms belong to the typical L-type. Maximum percentage removal was found to be 84% (124.40 mg/g) for MG dye concentration (30 mg/L) at pH 7.0 and 303 K with ACMOL dose 0.02 g/100 mL. The adsorption kinetics and equilibrium experimental data of MG dye adsorption on the ACMOL were well explained by the pseudo-second-order kinetics (R2 = 0.99) and Langmuir isotherm model (R2 = 0.99), respectively. The value of adsorption and desorption coefficient was found to be 0.036 min-1 and 0.025 mg min-1/L, respectively. Thermodynamic study showed the spontaneous (ΔG° = - 31.33, - 31.92, and - 32.49 kJ/mol at temperatures 303 K, 313 K, and 323 K, respectively) and exothermic (ΔH° = - 13.7 kJ/mol) nature of the adsorption with some structural changes occurring on the ACMOL surface (ΔS° = 58.198 J/K·mol).