Facile electrolysis-solvothermal synthesis of NiOx/graphene for enhanced ethanol oxidation to acetate.
Dalton Trans
; 53(9): 4237-4242, 2024 Feb 27.
Article
em En
| MEDLINE
| ID: mdl-38334161
ABSTRACT
In this work, low-crystalized and defective NiOx/graphene was synthesized by a facile electrolysis-solvothermal method. In the electrolytic process, Ni ions originate from the Ni anode, and graphene is produced from the graphite cathode. Then, Ni ions are reduced into oxides and deposited on graphene in the subsequent solvothermal process. The NiOx/graphene displays excellent electrocatalytic activity and selectivity for ethanol oxidation reaction to acetate. The peak current density was 296.5 mA cm-2 on a glassy carbon electrode. The FE of acetate was more than 93% at the potential range between 1.4 and 1.7 V. We propose that the mechanism is a cooperation between the chemical deprotonating process of ethanol by Ni3+ species and the electrochemical oxidation of the CH3CH2O* intermediate to acetate at the interface between NiOx and graphene.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Dalton Trans
Assunto da revista:
QUIMICA
Ano de publicação:
2024
Tipo de documento:
Article
País de afiliação:
China