Your browser doesn't support javascript.
loading
Columnar liquid crystals based on antiaromatic expanded porphyrins.
Nguyen, Duong D; Labella, Jorge; Laforga-Martín, Juan; Folcia, César L; Ortega, Josu; Torres, Tomás; Sierra, Teresa; Sessler, Jonathan L.
Afiliação
  • Nguyen DD; Department of Chemistry, The University of Texas at Austin, 105 E 24th Street, A5300, Austin, TX, 78712, USA. sessler@cm.utexas.edu.
  • Labella J; Department of Organic Chemistry, Universidad Autónoma de Madrid, Campus de Cantoblanco, C/Francisco Tomás y Valiente 7, Madrid 28049, Spain. jorge.labella@uam.es.
  • Laforga-Martín J; Department of Organic Chemistry, Universidad Autónoma de Madrid, Campus de Cantoblanco, C/Francisco Tomás y Valiente 7, Madrid 28049, Spain. jorge.labella@uam.es.
  • Folcia CL; Department of Physics, Faculty of Science and Technology, UPV/EHU, Bilbao, Spain.
  • Ortega J; Department of Physics, Faculty of Science and Technology, UPV/EHU, Bilbao, Spain.
  • Torres T; Department of Organic Chemistry, Universidad Autónoma de Madrid, Campus de Cantoblanco, C/Francisco Tomás y Valiente 7, Madrid 28049, Spain. jorge.labella@uam.es.
  • Sierra T; Institute for Advanced Research in Chemical Sciences (IAdChem), Universidad Autónoma de Madrid, Madrid 28049, Spain.
  • Sessler JL; IMDEA-Nanociencia, Campus de Cantoblanco, Madrid 28049, Spain.
Chem Commun (Camb) ; 60(25): 3401-3404, 2024 Mar 21.
Article em En | MEDLINE | ID: mdl-38440812
ABSTRACT
Three naphthorosarins, antiaromatic expanded porphyrins bearing different meso substituents (NRos 1-3), designed to self-assemble into columnar liquid crystalline (LC) structures, were synthesized and characterized using polarized optical microscopy (POM), differential scanning calorimetry (DSC), X-ray diffraction (XRD), as well as supporting computational calculations. The substituents were found to play a crucial role in modulating the LC behaviour.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: Estados Unidos País de publicação: Reino Unido

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: Estados Unidos País de publicação: Reino Unido