(Radio)Fluoro-iodination of Alkenes Enabled by a Hydrogen Bonding Donor Solvent.

Han, Junbin; Lu, Xiaolei; Chen, Li; Gong, Kehao; Xu, Bo; Zeng, Xiaojun

Han, Junbin; Lu, Xiaolei; Chen, Li; Gong, Kehao; Xu, Bo; Zeng, Xiaojun.

Afiliação

Han J; Institute of Radiation Medicine, Fudan University, Xietu Road 2094, Shanghai 200032, China.
Lu X; Institute of Radiation Medicine, Fudan University, Xietu Road 2094, Shanghai 200032, China.
Chen L; School of Chemistry and Chemical Engineering, Nanchang University, Nanchang, Jiangxi 330031, China.
Gong K; Institute of Radiation Medicine, Fudan University, Xietu Road 2094, Shanghai 200032, China.
Xu B; College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, North Renmin Road 2999, Shanghai 201620, China.
Zeng X; School of Chemistry and Chemical Engineering, Nanchang University, Nanchang, Jiangxi 330031, China.

Org Lett ; 26(16): 3435-3440, 2024 Apr 26.

Article em En | MEDLINE | ID: mdl-38629704

ABSTRACT

ABSTRACT

We have developed a widely applicable (radio)fluoro-iodination of alkenes using readily available and easily handled KF (18F). The reactions exhibited high functional group tolerance and needed only an ambient atmosphere. Furthermore, the resulting product could be further functionalized with various nucleophiles.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Org Lett Assunto da revista: BIOQUIMICA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: China País de publicação: Estados Unidos

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