Research progress of persulfate activation technology.

ABSTRACT

Persulfate-based advanced oxidation processes (PS-AOPs) have been widely investigated by academia and industry due to their high efficiency and selectivity for the removal of trace organic pollutants from complex water substrates. PS-AOPs have been extensively studied for the degradation of pesticides, drugs, halogen compounds, dyes, and other pollutants. Utilizing bibliometric statistics, this review presents a comprehensive overview of persulfate-based advanced oxidation technology research over the past decade. The number of published articles about persulfate activation has steadily increased during this time, reflecting extensive international collaboration. Furthermore, this review introduces the most widely employed strategies for persulfate activation reported in the past 10 years, including carbon material activation, photocatalysis, transition metal activation, electrochemical activation, ultrasonic activation, thermal activation, and alkali activation. Next, the potential activation mechanisms and influencing factors, such as persulfate dosage during activation, are discussed. Finally, the application of PS-AOPs in wastewater treatment and in situ groundwater treatment is examined. This review summarizes the previously reported experiences of persulfate-based advanced oxidation technology and presents the current application status of PS-AOPs in organic pollution removal, with the aim of avoiding misunderstandings and providing a solid foundation for future research on the removal of organic pollutants.