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Ni-Co hexacyanoferrate hollow nanoprism with CN vacancy for electrocatalytic benzyl alcohol oxidation.
Lv, Chenghang; Chen, Liang; Bai, Jingjing; Ruo, Hongyu; Pan, Yanlong; Xu, Shoudong; Chen, Jiaqi; Zhang, Ding; Guo, Chunli.
Afiliação
  • Lv C; College of Chemistry, Taiyuan University of Technology, Taiyuan 030024, P. R. China. chenliang@tyut.edu.cn.
  • Chen L; College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, P. R. China. guochunli@tyut.edu.cn.
  • Bai J; College of Chemistry, Taiyuan University of Technology, Taiyuan 030024, P. R. China. chenliang@tyut.edu.cn.
  • Ruo H; College of Chemistry, Taiyuan University of Technology, Taiyuan 030024, P. R. China. chenliang@tyut.edu.cn.
  • Pan Y; College of Chemistry, Taiyuan University of Technology, Taiyuan 030024, P. R. China. chenliang@tyut.edu.cn.
  • Xu S; College of Chemistry, Taiyuan University of Technology, Taiyuan 030024, P. R. China. chenliang@tyut.edu.cn.
  • Chen J; College of Chemical Engineering and Technology, Taiyuan University of Technology, Taiyuan 030024, P. R. China.
  • Zhang D; College of Chemistry, Taiyuan University of Technology, Taiyuan 030024, P. R. China. chenliang@tyut.edu.cn.
  • Guo C; School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430205, P. R. China.
Chem Commun (Camb) ; 60(46): 5952-5955, 2024 Jun 04.
Article em En | MEDLINE | ID: mdl-38764428
ABSTRACT
An innovative method to improve the oxidation efficiency of benzyl alcohol utilizes Ni-Co hexacyanoferrate hollow nanoprisms. Synthesized via a gentle self-sacrificial template method, this catalyst exhibits substantial catalytic activity and selectivity towards benzyl alcohol oxidation, facilitated by the strategic incorporation of Co to modulate CN vacancy density. Impressively, it achieves a current density of 10 mA cm-2 at 1.33 V and a remarkable 98% efficiency in benzyl alcohol conversion at 1.4 V.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article
Texto completo
Adicionar na Minha BVS
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article