Far-red fluorescence and chiroptical properties of pyrrolopyrrole aza-BODIPYs induced by the <i>B</i>,<i>O</i>-chelation.

Fukami, Shuhei; Mori, Shigeki; Harada, Takunori; Shimizu, Soji

Far-red fluorescence and chiroptical properties of pyrrolopyrrole aza-BODIPYs induced by the B,O-chelation.

Fukami, Shuhei; Mori, Shigeki; Harada, Takunori; Shimizu, Soji.

Afiliação

Fukami S; Department of Applied Chemistry, Graduate School of Engineering and Centre for Molecular Systems (CMS), Kyushu University, Fukuoka 819-0395, Japan. ssoji@cstf.kyushu-u.ac.jp.
Mori S; Advanced Research Support Centre (ADRES), Ehime University, Matsuyama 790-8577, Japan.
Harada T; Department of Integrated Science and Technology, Faculty of Science and Technology, Oita University, Oita 870-1192, Japan.
Shimizu S; Department of Applied Chemistry, Graduate School of Engineering and Centre for Molecular Systems (CMS), Kyushu University, Fukuoka 819-0395, Japan. ssoji@cstf.kyushu-u.ac.jp.

Chem Commun (Camb) ; 60(48): 6170-6173, 2024 Jun 11.

Article em En | MEDLINE | ID: mdl-38804674

ABSTRACT

ABSTRACT

A titanium-mediated aza-BODIPY synthesis using diketopyrrolopyrrole bearing o-anisyl substituents provided B,O-chelated pyrrolopyrrole aza-BODIPYs in a one-pot manner via ether bond cleavage and chelation of the resulting nucleophilic oxygen to the boron atom. The B,O-chelation not only induces the redshifts of absorption and fluorescence but also endows chiroptical properties.

Texto completo

Adicionar na Minha BVS

Imprimir

XML

PubMed Links

Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: Japão

Texto completo

Adicionar na Minha BVS

Imprimir

XML

PubMed Links

Buscar no Google