N-Heterocyclic carbene/palladium synergistic catalysis in organic synthesis.
Org Biomol Chem
; 22(23): 4613-4624, 2024 Jun 12.
Article
em En
| MEDLINE
| ID: mdl-38804684
ABSTRACT
The cooperation of two distinct catalytic cycles to activate different reactive centers leading to a chemical transformation has been classified as synergistic catalysis. The synergistic combination of NHC with palladium catalysis has emerged as a powerful strategy in the last few years. Merging the ability of NHCs to inverse the polarity of a functional group with the unique reactivity of palladium enables transformations that cannot be accomplished by either of these catalysts alone. Despite the associated challenges, such as quenching of catalysts, reactivity mismatch etc., significant development has been achieved in the field of NHC/Pd synergistic catalysis. The recent incorporation of photoredox catalysis with NHC/Pd synergistic catalysis has further advanced this area. This review highlights the developments made in the area of NHC/Pd synergistic catalysis.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Org Biomol Chem
Assunto da revista:
BIOQUIMICA
/
QUIMICA
Ano de publicação:
2024
Tipo de documento:
Article
País de afiliação:
Índia
País de publicação:
Reino Unido